diff --git a/docs/development/test-vectors.rst b/docs/development/test-vectors.rst
index 41f31a1ed0a2..69a6d006a607 100644
--- a/docs/development/test-vectors.rst
+++ b/docs/development/test-vectors.rst
@@ -300,6 +300,10 @@ Custom asymmetric vectors
   encrypted with ``pbeWithSHA1And128BitRC4``. The password is ``password``.
 * ``asymmetric/PKCS8/enc-rsa-pkcs8-pbkdf2-0iter.pem`` a PKCS8 encoded
   structure with an invalid PBKDF2 iteration count (zero).
+* ``asymmetric/MLDSA/mldsa44_pub.der`` and ``asymmetric/MLDSA/mldsa44_priv.der``
+  a PKCS8 encoded key pair for ML-DSA-44 generated by OpenSSL.
+* ``asymmetric/MLDSA/mldsa65_noseed_priv.der`` a PKCS8 encoded ML-DSA-65 private
+  key serialized without the seed.
 
 Key exchange
 ~~~~~~~~~~~~
diff --git a/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa44_priv.der b/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa44_priv.der
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index 000000000000..244192344fdc
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diff --git a/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa44_pub.der b/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa44_pub.der
new file mode 100644
index 000000000000..2598b11b9404
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diff --git a/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa65_noseed_priv.der b/vectors/cryptography_vectors/asymmetric/MLDSA/mldsa65_noseed_priv.der
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index 000000000000..ee05f2940e94
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